Biodiesel is a promising alternative fuel due to the shortness of fossil fuels. Design optimization of a microreactor for the production of biodiesel. In the present work, choline hydroxide as a basic ionic liquid catalyst was selected for biodiesel production in micro scale reactor. Astm international originally known as the american society for testing and. Ultrasoundassisted biodiesel production in microreactors 26 iranian journal of chemical engineering, vol. Algal companies specialized in biodiesel production the following is a list of companies developing processes. Algal companies specialized in biodiesel production the following is a list of companies developing processes for the production of biodiesel from algae oil. Microreactor was utilized to overcome numerous issues of the traditional methods for biodiesel production. In order to further improve biodiesel yield, an experimental design was employed using the boxbehnken method and analysis of variance. Usually a catalyst is used to mediate the reaction and bring out quicker reaction rate 1.
Microreactor technology, however, has proved to be a benchmark to serve this purpose. Hence, there is need for optimal, efficient and safe production of biodiesel from microalgae. In this work, we propose a project for the design and construction of a biodiesel microreactor. Economic wise, regional production of microalgae and processing into biofuels will provide great benefits to rural communities. New heterogeneous process for continuous biodiesel production. Majid mohadesi, babak aghel, mahmoud maleki and ahmadreza ansari, production of biodiesel from waste cooking oil using a homogeneous catalyst. Proceedings of the asme 2011 international design engineering technical conferences and computers and information in engineering conference. Numerical investigation of biodiesel production in capillary microreactor. Continuous biodiesel production with biodiesel was able to. Introduction biodiesel referees to a dieselequivalent, processed fuel derived from biological. Its primary advantages are that it is one of the most renewable fuels currently available and it is also nontoxic and biodegradable. Biodiesel production from soybean oil using ionic liquid as a. Numerical investigation of biodiesel production in capillary. The main issue in this study is to find the effects of methanoloil.
Pdf due to a rise in global demand for energy and an increase in greenhouse gases, biodiesel has been accepted as an alternative fuel. Finally, continuous biodiesel production was studied in the microreactors in order. This can be produced from vegetable oils, animal fats, microalgal oils, waste products of vegetable oil refinery or animal rendering, and used. Numerical simulation can play an integral role in evaluating new reactor designs or optimizing existing ones. The objective of this study was to investigate the biodiesel production process from refined palm oil. Optimization of biodiesel production by various plant. Using a wire coil insert for biodiesel production enhancement in a microreactor. Transesterification is a principal chemical reaction that occurs in biodiesel production. A flowthrough enzymatic microreactor for the rapid conversion of triacylglycerols into fatty acid. Production of microreactor systems by additive manufacturing technology 1university of zagreb, faculty of chemical engineering and technology, zagreb, croatia abstract microreactor. This study focuses on maximizing the yield of microfluidic biodiesel production through the use of microreactors. Continuous biodiesel production with biodiesel was. In the present study, experimental work on continuous biodiesel production using a tshaped microreactor was carried out. The components that support combustion in the oil are the basis for biodiesel.
The maximum conversion obtained was 98%, with residence time of 180 s, at 60 c, 1% wt catalyst concentration. Biodiesel production from soybean oil using ionic liquid as a catalyst in a microreactor 106 iranian journal of chemical engineering, vol. Maurizio carlini id, sonia castellucci id and andrea mennuni id. Biodiesel characterization characterization of fame in biodiesel. Unlike companies which manufacture biodiesel production equipment biodiesel processor based on outdated, tank technologies, which have been used for over a century, our. Biodiesel production, properties, and feedstocks bryan r. Microtechnology new paradigm for process industries. Design of a microreactor for biodiesel production from algae.
The monthly biodiesel production report provides data on operations of the u. Numerical simulation of biodiesel synthesis in a continuous. In this paper, application and possibilities of microreactor technology in biodiesel production have been discussed. Development of microreactors applied on biodiesel synthesis. Optimization of biodiesel production by various plant sources. Development and assessment of microreactors applied to biodiesel.
The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. Combined production of biodiesel and nontoxic cottonseed meal using twostep twophase solvent extraction. Fourier transform infrared spectroscopy was used to investigate the functional groups present in biodiesel. The main issue in this study is to find the effects of methanoloil molar ratio, catalyst concentration, reaction time and reaction temperature on the percentage of methyl esters conversion fame %. Due to small holdup of hazardous chemicals, mr provides safety. Purchase advances in biodiesel production 1st edition.
Pdf design of a microreactor for biodiesel production from. Biodiesel characterization characterization of fame in biodiesel samples was determined by a hp 6890 gas chromatograph with a flame ionization detector fid. Pdf there is a growing interest in the production of biofuels mainly because of environmental protection and energy supply reasons. Biodiesel has become an increasingly popular fossil fuel substitute in recent years. Microreactor mr technology in biodiesel production provides production betw een 10 and 100 times faster tha n traditional methods.
Therefore, refined palm oil and ethyl acetate were used as an oil feedstock and. This paper discusses the alternative ways to optimize biodiesel production. The proposed mathematical model predicted the trend of enzyme catalysed transesterification in a microreactor very well and it was used for further process optimisation. Microreactors for production of veins and arteries.
One such energy source is referred to as biodiesel. Kohcatalyzed synthesis of biodiesel was carried out in capillary microreactors with inner diameters of 0. Biodiesel is a form of diesel fuel derived from plants or animals and consisting of longchain fatty acid esters. First, different oils from different plant sources were compared to see the degree of conversion in transesterification reaction and the purity of biodiesel produced. The application of microreactors on biodiesel production, may provide a solution for this purpose, for short residence times, high production efficiency and low operating cost and energy consumption in biodiesel production via transesterification. Us20090165366a1 microreactor process for making biodiesel. Production of microreactor systems by additive manufacturing. Hence, there is need for optimal, efficient and safe production of.
The %fame was calculated by gas chromatography using methyl arachidate as an internal standard. Development of a millimetrically scaled biodiesel transesterification device that relies on dropletbased coaxial fluidics. Small scale biodiesel production feasibility report. Design optimization of a microreactor for the production of. Thermal and fluid dynamic analysis within a batch microreactor. Constant attempts are being made to develop new technology that increases the efficiency and yield of. It is typically made by chemically reacting lipids such as animal fat, soybean oil. Conclusion this proof of principle experiment demonstrates the utility of microfluidics in the production of biodiesel. This report is an overview of the biodiesel production process on a smallscale basis. The transesterification of sunflower oil using sodium hydroxide, as a catalyst, in a microreactor as a continuous reactor was investigated. Han, wei, charoenwat, rachaneewan, and dennis, brian h.
Design optimization of a microreactor for the production. Org, a leading organization in biodiesel research and marketing. Third, biodiesel is a renewable and clean burning energy source. Biodiesel production during february 2020 was 2 million gallons lower than production in january 2020. New heterogeneous process for continuous biodiesel production in. Kinetic parameter estimation and mathematical modelling of. Cad model of the microreactor rial to build up, which can clog the duct. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer. On the other hand, this microreactor type was discarded due to clogging and a ptfe tubular microreactor was proposed as a better solution for biodiesel production.
Membrane microreactor in biocatalytic transesterification of. Second, microreactor is proposed as an alternative to conventional, batch reactor in producing. Triolein with a 3 molar equivalents of methanol, 100 % conversion triolein to methyl oleate. Pdf design of a microreactor for biodiesel production. Catalysts can be used to facilitate biodiesel production, such as metal oxides, metal hydroxides, metal carbonates, alcoholic metal carbonates, alkoxides, mineral acids and enzymes. Ultrasoundassisted biodiesel production in microreactors. Biodiesel has one of the highest energy balance of any liquid fuel.
Jun 12, 2012 han, wei, charoenwat, rachaneewan, and dennis, brian h. Biodiesel production from soybean oil using ionic liquid. We developed a novel biocatalytic membrane microreactor bmm for continuous transesterification by utilizing an asymmetric membrane as an enzymecarrier for. Biodiesel production was carried out 15 times faster in a tubular microreactor tmr than a wellmixed batch reactor. Therefore, refined palm oil and ethyl acetate were used as an oil feedstock and reactant in the present study. Researchers believe that implementation of this technology into biodiesel production could be a next big breakthrough not only in process intensification but also in process economics. Basics of biodiesel production biodiesel is an alternative fuel for diesel engines that is gaining attention in the united states after reaching a considerable level of success in europe. Micromachines free fulltext kinetic parameter estimation. Jul 18, 2016 development of a millimetrically scaled biodiesel transesterification device that relies on dropletbased coaxial fluidics.
Fourth, smallscale biodiesel production does not take more energy to create than it gives back. Biodiesel production from the midwest region petroleum administration for defense district 2 accounted for 75 percent of the united states total. Constant attempts are being made to develop new technology that increases the efficiency and yield of biodiesel production units. The canadian journal of chemical engineering, published by wiley on behalf of the canadian society for chemical engineering, is the forum for publication of high quality original research. A cellular manufacturing process for a fullscale biodiesel microreactor. Although biodiesel production has been commercialized in several countries, it still requires a clean, effective, and environmentfriendly technology to make it costeffective and increase its competency against conventional fossil fuels. New heterogeneous process for continuous biodiesel. Mar 23, 2015 biodiesel production produced by transesteri. Enzymatic approach to biodiesel production journal of.
Pdf microreactor technology for biodiesel production. Optimization of biodiesel production from soybean oil in a. Numerical investigation of biodiesel production in. Pdf design of a microreactor for biodiesel production from algae. Oil conversion to biodiesel typically increases with increasing mean microreactor residence time. Sep 29, 2007 the need for alternative energy sources that combine environmental friendliness with biodegradability, low toxicity, renewability, and less dependence on petroleum products has never been greater. Design of a microreactor for biodiesel production from. Investigation of factors affect biodiesel production in. We developed a novel biocatalytic membrane microreactor bmm for continuous. Production of biodiesel from waste vegetable oil via km. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. D deng, s optimization of biodiesel production from edible and nonedible vegetable oils. Microreactor manufactured on zortrax m200 printer, visible penetration of blue colored fluid into microreactor mass between the layers engeneering power dd 29 19.
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